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|Section2= |Section3= |Section7= |Section8= }} Titanium tetraiodide is an inorganic compound with the formula TiI4. It is a black volatile solid, first reported by Rudolph Weber in 1863.〔 〕 It is an intermediate in the Van Arkel process for the purification of titanium. ==Physical properties== TiI4 is a rare molecular binary metal iodide, consisting of isolated molecules of tetrahedral Ti(IV) centers. The Ti-I distances are 261 pm.〔 〕 Reflecting its molecular character, TiI4 can be distilled without decomposition at one atmosphere; this property is the basis of its use in the Van Arkel process. The difference in melting point between TiCl4 (m.p. -24 °C) and TiI4 (m.p. 150 °C) is comparable to the difference between the melting points of CCl4 (m.p. -23 °C) and CI4 (m.p. 168 °C), reflecting the stronger intermolecular van der Waals bonding in the iodides. Two polymorphs of TiI4 exist, one of which is highly soluble in organic solvents. In the less soluble cubic form, the Ti-I distances are 261 pm.〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Titanium tetraiodide」の詳細全文を読む スポンサード リンク
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